Two alumni of the Buffyverse on 'Supernatural,' playing a married couple? Are the fine folks behind the Winchester chronicles trying to make our heads explode? If so, mission accomplished. Charisma Carpenter (a.k.a. Cordelia Chase), and James Marsters (the artist formerly known as Spike) will play a witch and her suffering spouse in the fifth episode of the season. No word on whether Marsters will wear Spike's leather duster, but that might just be too much genre goodness in one show.

'Supernatural' Season 7 premieres Fri., Sept. 23, 9PM ET on The CW