Good chemistry between TV couples is a rare commodity, but when Robert Buckley and Kim Raver heat up the screen as Kirby and Nico on Lipstick Jungle, there's some major fireworks flying around.

Much of that spark can be attributed to Buckley, who inhabits the role of Kirby so well that it hardly seems like he's playing a part. Buckley took over the role from Will Toale, who played the part in the pilot episode.

The 26-year-old actor really hasn't been on the TV scene all that long. He got his start playing two roles on MyNetworkTV prime time dramas: photographer Michael Bauer on 2006's Fashion House; and Matthew Wakefield on 2007's American Heiress.

As we all get ready to welcome in the new CW network, it stands to reason that the merger must have left a few stations out there holding the bag. What is to become of them? The answer for some is that they will now be a part of News Corporation's myNetworkTV. The network begins airing its two original programs Tuesday, September 5th.

Those programs are Desire and Fashion House. Modeled after the popular telenovelas, each show will run five days a week, Monday through Friday, with a recap on Saturday. Rather than the endless run that normal American soap operas have, the myNetworkTV shows are each planned to run 65 episodes. As they come crashing to what promises to be a hectic conclusion after 13 weeks, two new shows will debut to run for the next 13.

Desire kicks off the night at 8PM. It is the story of brothers Louis and Alex Thomas. On the run from the mob, they make their way to Los Angeles. There, they both fall for the same woman and complications ensue as they deal with that and the mob gets ever closer. Desire is adapted from 2004's Mesa Para Tres (Table For Three).